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A molecule is the smallest amount of a chemical substance that can exist. If a molecule were split into smaller pieces, it would be a different substance.
Molecules are made up of atoms that are stuck together in a particular shape or form. Not all combinations of atoms are equally possible; atoms make certain shapes in preference to others. Also, they have different valency. For example, oxygen atoms always have two bonds with other atoms, carbon atoms always have four bonds with other atoms, and nitrogen atoms always have three bonds with other atoms.